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Tricoordinate Coinage Metal Complexes with a Redox‐Active Tris‐(Ferrocenyl)triazine Backbone Feature Triazine–Metal Interactions

Straube, Axel ; Coburger, Peter ; Ringenberg, Mark R. ; Hey‐Hawkins, Evamarie


2,4,6-Tris(1-diphenylphosphanyl-1'-ferrocenylene)-1,3,5-triazine (1) coordinates all three coinage metal(I) ions in a 1:1 tridentate coordination mode. The C-3-symmetric coordination in both solid state and solution is stabilised by an uncommon cation-pi interaction between the triazine core and the metal cation. Intramolecular dynamic behaviour was observed by variable-temperature NMR ...


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