Go to content
UR Home

Cooperative H–X Bond Activation by Electron‐Precise Aluminium and Gallium Compounds Incorporating β‐Diketiminate Ligands

Hitzfeld, Patrick S. ; Kretschmer, Robert



Abstract

The reaction pathways of the cooperative activation of protic, hydridic, and apolar H-X bonds by electron-precise Al and Ga beta-diketiminates have been probed by means of DFT calculations. Different mechanistic scenarios have been identified and range from concerted bimolecular to associative termolecular mechanisms depending on the nature of the H-X bond. The importance of distortion in the transition-state structure for catalyst design is emphasised.


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de
0941 943 4239

Dissertations: dissertationen@ur.de
0941 943 3904

Research data: daten@ur.de
0941 943 4239

Contact persons