Startseite UR

Cooperative H–X Bond Activation by Electron‐Precise Aluminium and Gallium Compounds Incorporating β‐Diketiminate Ligands

Hitzfeld, Patrick S. ; Kretschmer, Robert



Zusammenfassung

The reaction pathways of the cooperative activation of protic, hydridic, and apolar H-X bonds by electron-precise Al and Ga beta-diketiminates have been probed by means of DFT calculations. Different mechanistic scenarios have been identified and range from concerted bimolecular to associative termolecular mechanisms depending on the nature of the H-X bond. The importance of distortion in the transition-state structure for catalyst design is emphasised.


Nur für Besitzer und Autoren: Kontrollseite des Eintrags
  1. Universität

Universitätsbibliothek

Publikationsserver

Kontakt:

Publizieren: oa@ur.de
0941 943 -4239 oder -69394

Dissertationen: dissertationen@ur.de
0941 943 -3904

Forschungsdaten: datahub@ur.de
0941 943 -5707

Ansprechpartner