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Pb6O5(NO3)2: A Nonlinear Optical Oxynitrate Structurally Based on Lead Oxide Framework

Charkin, Dmitry O. ; Borisov, Artem S. ; Plokhikh, Igor V. ; Stefanovich, Sergey Yu. ; Zadoya, Anastasiya I. ; Zaloga, Alexander N. ; Semenova, Tatiana F. ; Siidra, Oleg I.



Abstract

A high second harmonic generation response is demonstrated by a Pb6O5(NO3)(2) lead oxynitrate whose identity was verified upon reinvestigation of the PbO-Pb(NO3)(2) system. Its crystal structure exhibits a unique cationic [Pb6O5](2+) framework hosting orientationally ordered NO3- triangles in the channels. Easy preparation and high thermal stability (until similar to 500 degrees C in air) suggest it to be a new promising NLO material.


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