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EuNi2P4, the first magnetic unconventional clathrate prepared via a mechanochemically assisted route

Plokhikh, Igor V. ; Khan, Nazir ; Tsirlin, Alexander A. ; Kuznetsov, Alexey N. ; Charkin, Dmitri O. ; Shevelkov, Andrei V. ; Pfitzner, Arno


For the first time, a magnetic unconventional clathrate EuNi2P4 has been prepared from the elements via a combined mechanochemical and solid-state route. Its crystal and electronic structure, magnetic and transport properties as well as lattice dynamics were elucidated. It crystallizes in the orthorhombic space group Fddd (Z = 8) with unit cell parameters a = 5.1852(1) angstrom, b = 9.4834(1) ...


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