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Dehydration Determines Hydrotropic Ion Affinity for Zwitterionic Micelles

Mortara, Laura ; Chaimovich, Hernan ; Cuccovia, Iolanda M. ; Horinek, Dominik ; Lima, Filipe S.


Specific ion effects in zwitterionic micelles, especially for anions, are evident in reaction kinetics, zeta potential, and critical micelle concentration measurements. However, anion adsorption to zwitterionic micelles does not produce significant changes in shape, aggregation number, or interfacial hydration. Here we used molecular dynamics simulation of systems containing sulfobetaine ...


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