Exploiting Cooperative Catalysis for the On-surface Synthesis of Linear Heteroaromatic Polymers via Selective C-H Activation

URN to cite this document:: urn:nbn:de:bvb:355-epub-510562
DOI to cite this document:: 10.5283/epub.51056

Liu, Xunshan ; Matej, Adam

; Kratky, Tim

; Mendieta-Moreno, Jesús I. ; Günther, Sebastian ; Mutombo, Pingo ; Decurtins, Silvio ; Aschauer, Ulrich ; Repp, Jascha

; Jelinek, Pavel ; Liu, Shi-Xia ; Patera, Laerte L.

License: Creative Commons Attribution Non-commercial No Derivatives 4.0
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Date of publication of this fulltext: 02 Dec 2021 05:42

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Abstract

Regiospecific C-H activation is a promising approach to achieve extended polymers with tailored structures. While a recent on-surface synthetic approach has enabled regioselective homocoupling of heteroaromatic molecules, only small oligomers have been achieved. Herein, selective C-H activation for dehydrogenative C-C couplings of hexaazatriphenylene by Scholl reaction is reported for the first ...