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Molecular Scissors for Tailor‐Made Modification of Siloxane Scaffolds

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Götz, Tobias ; Falk, Alexander ; Bauer, Jonathan O.
License: Creative Commons Attribution Non-commercial No Derivatives 4.0
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Date of publication of this fulltext: 02 Dec 2021 06:37

This publication is part of the DEAL contract with Wiley.


The controlled design of functional oligosiloxanes is an important topic in current research. A consecutive Si-O-Si bond cleavage/formation using siloxanes that are substituted with 1,2-diaminobenzene derivatives acting as molecular scissors is presented. The method allows to cut at certain positions of a siloxane scaffold forming a cyclic diaminosilane or -siloxane intermediate and then to ...


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