Molecular Scissors for Tailor‐Made Modification of Siloxane Scaffolds

URN to cite this document:: urn:nbn:de:bvb:355-epub-510759
DOI to cite this document:: 10.5283/epub.51075

Götz, Tobias ; Falk, Alexander ; Bauer, Jonathan O.

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Date of publication of this fulltext: 02 Dec 2021 06:37

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Abstract

The controlled design of functional oligosiloxanes is an important topic in current research. A consecutive Si−O−Si bond cleavage/formation using siloxanes that are substituted with 1,2-diaminobenzene derivatives acting as molecular scissors is presented. The method allows to cut at certain positions of a siloxane scaffold forming a cyclic diaminosilane or -siloxane intermediate and then to ...