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- URN to cite this document:
- urn:nbn:de:bvb:355-epub-511354
- DOI to cite this document:
- 10.5283/epub.51135
Abstract
The synthesis and reactivity of the tert-butyl-substituted arsanylborane tBuAsHBH2 ⋅ NMe3 (1) stabilized by a Lewis base (LB) are reported. Compound 1 is obtained by the reaction of in situ generated NatBuAsH with IBH2 ⋅ NMe3. By the reaction of 1 with Lewis acids the neutral compounds BBr3 ⋅ tBuAsHBH2 ⋅ NMe3 (2) and BH3 ⋅ tBuAsHBH2 ⋅ NMe3 (3) as well as coordination products towards Group 6 ...

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