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Nanoscale π-conjugated ladders

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Meißner, Stefanie A. ; Eder, Theresa ; Keller, Tristan J. ; Hofmeister, David A. ; Spicher, Sebastian ; Jester, Stefan-S. ; Vogelsang, Jan ; Grimme, Stefan ; Lupton, John M. ; Höger, Sigurd
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Date of publication of this fulltext: 23 Dec 2021 05:47


It is challenging to increase the rigidity of a macromolecule while maintaining solubility. Established strategies rely on templating by dendrons, or by encapsulation in macrocycles, and exploit supramolecular arrangements with limited robustness. Covalently bonded structures have entailed intramolecular coupling of units to resemble the structure of an alternating tread ladder with rungs ...


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