Synthetic Molecular Photoelectrochemistry: New Frontiers in Synthetic Applications, Mechanistic Insights and Scalability.
Synthetische molekulare Photoelektrochemie: neue synthetische Anwendungen, mechanistische Einblicke und Möglichkeiten zur Skalierung

URN to cite this document:

urn:nbn:de:bvb:355-epub-516660 Copy

DOI to cite this document:

10.5283/epub.51666 Copy

Wu, Shangze ; Kaur, Jaspreet ; Karl, Tobias A. ; Tian, Xianhai ; Barham, Joshua P.

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Date of publication of this fulltext: 15 Feb 2022 06:19

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Details

Item type:	Article
Open Access Type:	DEAL (Wiley)
Journal or Publication Title:	Angewandte Chemie International Edition
Publisher:	Wiley
Volume:	61
Page Range:	e202107811
Date:	3 September 2021
Institutions:	Chemistry and Pharmacy > Institut für Organische Chemie
Projects (Historical):	Alexander von Humboldt-Stiftung (Grant number: Sofja Kovalevskaja Award; Grant recipient: Joshua Philip Barham)
Identification Number:	Value Type 10.1002/anie.202107811 DOI 10.1002/ange.202107811 DOI
Keywords:	electrophotocatalysis, hydrogen atom transfer, photoelectrochemistry, photoredox catalysis, preassembly
Dewey Decimal Classification:	500 Science > 540 Chemistry & allied sciences
Status:	Published
Refereed:	Yes, this version has been refereed
Created at the University of Regensburg:	Yes
Item ID:	51666

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Abstract

Synthetic photoelectrochemistry (PEC) offers new prospects for the generation and handling of reactive intermediates. PEC permits selective single-electron transfer (SET) reactions in a much greener way and broadens the redox window of possible transformations. This Review discusses the combination of PEC with other reactivity paradigms, scalability up to multigram scale, novel selectivities in ...

Abstract

Synthetic photoelectrochemistry (PEC) offers new prospects for the generation and handling of reactive intermediates. PEC permits selective single-electron transfer (SET) reactions in a much greener way and broadens the redox window of possible transformations. This Review discusses the combination of PEC with other reactivity paradigms, scalability up to multigram scale, novel selectivities in SET super-oxidations/reductions and the importance of precomplexation.
Synthetic photoelectrochemistry (PEC) is receiving increasing attention as a new frontier for the generation and handling of reactive intermediates. PEC permits selective single-electron transfer (SET) reactions in a much greener way and broadens the redox window of possible transformations. Herein, the most recent contributions are reviewed, demonstrating exciting new opportunities, namely, the combination of PEC with other reactivity paradigms (hydrogen-atom transfer, radical polar crossover, energy transfer sensitization), scalability up to multigram scale, novel selectivities in SET super-oxidations/reductions and the importance of precomplexation to temporally enable excited radical ion catalysis.

Die synthetische Photoelektrochemie (PEC) bietet neue Möglichkeiten für die Erzeugung und Handhabung reaktiver Zwischenstufen. Selektive Einelektronentransferreaktionen (SET) auf wesentlich umweltfreundlichere Weise und die Erweiterung des Redoxfensters erwecken Aufmerksamkeit. Dieser Aufsatz befasst sich mit den diesbezüglich neusten Beiträgen. Besprochen werden die Kombination von PEC mit anderen Reaktivitäten (Wasserstoffatomtransfer, radical–polar crossover, Energietransfer-Sensibilisierung), die Skalierbarkeit bis zum Multigramm-Maßstab, neuartige Selektivitäten bei SET-Superoxidationen/Reduktionen und die Bedeutung der Vorkomplexierung, um die Katalyse angeregter Radikalionen zeitlich zu ermöglichen.

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Metadata last modified: 20 Sep 2023 04:26

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