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Diphosphorus Release and Heterocumulene Oligomerisation by Nickel Complexes

URN to cite this document:
urn:nbn:de:bvb:355-epub-519348
DOI to cite this document:
10.5283/epub.51934
Hierlmeier, Gabriele ; Wolf, Robert
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Date of publication of this fulltext: 16 Mar 2022 05:35

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Abstract

The generation of diphosphorus molecules P2 under mild conditions in solution is a useful strategy to generate diphosphines via [4+2] cycloadditions. We recently described the release of P2 units from the nickel butterfly complex [{(IMes)Ni(CO)}2(μ2,η2:η2-P2)] (IMes=1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene) upon addition of CO gas. Herein, we developed an alternative protocol for the ...

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