| License: Creative Commons Attribution Non-commercial 4.0 PDF - Published Version Early View (5MB) |
- URN to cite this document:
- urn:nbn:de:bvb:355-epub-519348
- DOI to cite this document:
- 10.5283/epub.51934
This publication is part of the DEAL contract with Wiley.
Abstract
The generation of diphosphorus molecules P-2 under mild conditions in solution is a useful strategy to generate diphosphines via [4+2] cycloadditions. We recently described the release of P-2 units from the nickel butterfly complex [{(IMes)Ni(CO)}(2)(mu(2),eta(2):eta(2)-P-2)] (IMes=1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene) upon addition of CO gas. Herein, we developed an alternative ...

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