Go to content
UR Home

Photocatalyzed Dehydrogenation of Aliphatic N‑Heterocycles Releasing Dihydrogen

Ritu, ; Das, Saikat ; Tian, Ya-Ming ; Karl, Tobias ; Jain, Nidhi ; König, Burkhard



Abstract

We report the iridium–nickel dual photocatalytic acceptorless and redox neutral dehydrogenation of aliphatic heterocycles yielding cyclic alkenes without overoxidation at room temperature. Excitation of the iridium photocatalyst initiates the formation of a nickel hydride intermediate that yields alkenes and H2 via β-hydride elimination. The reaction proceeds regioselectively and the scope was ...

plus


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de
0941 943 4239

Dissertations: dissertationen@ur.de
0941 943 3904

Research data: daten@ur.de
0941 943 4239

Contact persons