α‐Amino Radical Halogen Atom Transfer Agents for Metallaphotoredox‐Catalyzed Cross‐Electrophile Couplings of Distinct Organic Halides

URN to cite this document:: urn:nbn:de:bvb:355-epub-528124
DOI to cite this document:: 10.5283/epub.52812

Tian, Xianhai ; Kaur, Jaspreet ; Yakubov, Shahboz ; Barham, Joshua Philip

License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 30 Aug 2022 04:33

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Abstract

alpha-Amino radicals from simple tertiary amines were employed as halogen atom transfer (XAT) agents in metallaphotoredox catalysis for cross-electrophile couplings of organic bromides with organic iodides. This XAT strategy proved to be efficient for the generation of carbon radicals from a range of partners (alkyl, aryl, alkenyl, and alkynyl iodides). The reactivities of these radical ...