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A Homoleptic Diphosphatetrahedrane Nickel(0) Complex

URN to cite this document:
urn:nbn:de:bvb:355-epub-530737
DOI to cite this document:
10.5283/epub.53073
Uttendorfer, Maria K. ; Hierlmeier, Gabriele ; Wolf, Robert
Date of publication of this fulltext: 20 Oct 2022 05:46

This publication is part of the DEAL contract with Wiley.


Abstract

The stable diphosphatetrahedrane, (tBuCP)2, was isolated only recently, and its coordination chemistry has been little explored so far. Herein we report the synthesis of [Ni{η2-(tBuCP)2}3] (1) by CO substitution of Ni(CO)4 with (tBuCP)2. Single-crystal X-ray diffraction studies revealed that 1 features three intact diphosphatetrahedrane molecules coordinated via their P−P bonds to a single ...

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