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Reusable Copper Catechol‐based Porous Polymers for the Highly Efficient Heterogeneous Catalytic Oxidation of Secondary Alcohols

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Henrion, Mickaël ; Mohr, Yorck ; Janssens, Kwinten ; Smolders, Simon ; Bugaev, Aram L. ; Usoltsev, Oleg A. ; Quadrelli, Elsje Alessandra ; Wisser, Florian M. ; De Vos, Dirk E. ; Canivet, Jérôme
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Date of publication of this fulltext: 20 Oct 2022 06:28

This publication is part of the DEAL contract with Wiley.


New catechol-based porous polymers were synthesized and used as platforms for the heterogenization of molecular Cu complexes. The resulting Cu@CatMP-1 materials proved to be highly stable and performing catalysts for the oxidation of secondary alcohols with turnover numbers up to 6000, about 1 to 2 orders of magnitude higher than the current relevant state of the art, using catalyst loadings as ...


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