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Transition-Metal-Stabilized Heavy Tetraphospholide Anions

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Kelly, John A. ; Streitferdt, Verena ; Dimitrova, Maria ; Westermair, Franz F. ; Gschwind, Ruth Maria ; Berger, Rafael J. F. ; Wolf, Robert
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Date of publication of this fulltext: 04 Nov 2022 08:44


Phosphorus analogues of the ubiquitous cyclopenta-dienyl (Cp) are a rich and diverse family of compounds, which have found widespread use as ligands in organometallic complexes. By contrast, phospholes incorporating heavier group 14 elements (Si, Ge, Sn, and Pb) are hardly known. Here, we demonstrate the isolation of the first metal complexes featuring heavy cyclopentadienyl anions SnP42-and ...


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