Bidentate Substrate Binding in Brønsted Acid Catalysis: Structural Space, Hydrogen Bonding and Dimerization

URN to cite this document:: urn:nbn:de:bvb:355-epub-532804
DOI to cite this document:: 10.5283/epub.53280

Gramüller, Johannes ; Dullinger, Philipp ; Horinek, Dominik

; Gschwind, Ruth M.

License: Creative Commons Attribution Non-commercial 3.0
PDF - Published Version
(1MB)

Date of publication of this fulltext: 19 Dec 2022 09:35

Alternative links to fulltext:DOI Publisher

Details

Preview

Export bibliographical data

Abstract

BINOL derived chiral phosphoric acids (CPAs) are a prominent class of catalysts in the field of asymmetric organocatalysis, capable of transforming a wide selection of substrates with high stereoselectivities. Exploiting the Brønsted acidic and basic dual functionality of CPAs, substrates with both a hydrogen bond acceptor and donor functionality are frequently used as the resulting bidentate ...