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Bidentate Substrate Binding in Brønsted Acid Catalysis: Structural Space, Hydrogen Bonding and Dimerization

URN to cite this document:
urn:nbn:de:bvb:355-epub-532804
DOI to cite this document:
10.5283/epub.53280
Gramüller, Johannes ; Dullinger, Philipp ; Horinek, Dominik ; Gschwind, Ruth M.
Date of publication of this fulltext: 19 Dec 2022 09:35



Abstract

BINOL derived chiral phosphoric acids (CPAs) are a prominent class of catalysts in the field of asymmetric organocatalysis, capable of transforming a wide selection of substrates with high stereoselectivities. Exploiting the Brønsted acidic and basic dual functionality of CPAs, substrates with both a hydrogen bond acceptor and donor functionality are frequently used as the resulting bidentate ...

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