Steering the Ultrafast Opening and Closure Dynamics of a Photochromic Coordination Cage by Guest Molecules

URN to cite this document:: urn:nbn:de:bvb:355-epub-533046
DOI to cite this document:: 10.5283/epub.53304

Artmann, Kevin ; Li, Ru‐Jin ; Juber, Selina ; Benchimol, Elie

; Schäfer, Lars V. ; Clever, Guido H.

; Nuernberger, Patrick

License: Creative Commons Attribution Non-commercial 4.0
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Date of publication of this fulltext: 08 Dec 2022 05:52

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Abstract

Photochemical studies on supramolecular hosts that can encapsulate small guest molecules commonly focus on three aspects: photoswitching the cage to release or trap the guest, the effect of the confining environment on the guest, and light-induced exciton or charge transfer within the cage structure. Here, we exploit ultrafast spectroscopy to address how the guest alters the photoswitching ...