Enforced Electronic-Donor-Acceptor Complex Formation in Water for Photochemical Cross-Coupling

URN to cite this document:: urn:nbn:de:bvb:355-epub-536902
DOI to cite this document:: 10.5283/epub.53690

Tian, Ya-Ming

; Hofmann, Evamaria ; Meneszes-da-Silva, Wagner ; Touraud, Didier

; Gschwind, Ruth Maria

; Kunz, Werner

; König, Burkhard

License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 08 Feb 2023 05:31

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Abstract

The amino alcohol meglumine solubilizes organic compounds in water and enforces the formation of electron donor acceptor (EDA) complexes of haloarenes with indoles, anilines, anisoles or thiols, which are not observed in organic solvents. UV-A photoinduced electron transfer within the EDA complexes induces the mesolytic cleavage of the halide ion and radical recombination of the arenes leading, ...