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Enforced Electronic-Donor-Acceptor Complex Formation in Water for Photochemical Cross-Coupling

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Tian, Ya-Ming ; Hofmann, Evamaria ; Meneszes-da-Silva, Wagner ; Touraud, Didier ; Gschwind, Ruth Maria ; Kunz, Werner ; König, Burkhard
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Date of publication of this fulltext: 08 Feb 2023 05:31

This publication is part of the DEAL contract with Wiley.


The amino alcohol meglumine solubilizes organic compounds in water and enforces the formation of electron donor acceptor (EDA) complexes of haloarenes with indoles, anilines, anisoles or thiols, which are not observed in organic solvents. UV-A photoinduced electron transfer within the EDA complexes induces the mesolytic cleavage of the halide ion and radical recombination of the arenes leading, ...


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