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Enforced Electronic-Donor-Acceptor Complex Formation in Water for Photochemical Cross-Coupling

Tian, Ya-Ming ; Hofmann, Evamaria ; Meneszes-da-Silva, Wagner ; Touraud, Didier ; Gschwind, Ruth Maria ; Kunz, Werner ; König, Burkhard


The amino alcohol meglumine solubilizes organic compounds in water and enforces the formation of electron donor acceptor (EDA) complexes of haloarenes with indoles, anilines, anisoles or thiols, which are not observed in organic solvents. UV-A photoinduced electron transfer within the EDA complexes induces the mesolytic cleavage of the halide ion and radical recombination of the arenes leading, ...


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