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Li₃Tr As₂ ( Tr =Al, Ga, In) – Derivatives of the antifluorite type structure, conductivities and electronic structures

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Wegner, Florian ; Kamm, Franziska ; Pielnhofer, Florian ; Pfitzner, Arno
Date of publication of this fulltext: 15 Feb 2023 12:04

This publication is part of the DEAL contract with Wiley.


Li3AlAs2, Li3GaAs2 and Li3InAs2 were obtained from the elements via high temperature synthesis. Li3AlAs2 and Li3GaAs2 crystallize in a distorted 2 ⋅ 2 ⋅ 1 superstructure of the antifluorite structure type. The orthorhombic crystal structure is isotypic to Li3AlP2 and Li3GaP2, space group Cmce (No. 64) showing layers of condensed TrAs4-tetrahedra (Tr=Al, Ga). Li3InAs2 crystallizes isotypic to ...


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