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[K([2.2.2]‐crypt)]K[Pt 3 (μ 2 ‐CO) 3 (PPh 3 ) 3 ] ⋅ 3NH 3 – A New Chini ‐Type Platinum Carbonyl Complex

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Tiefenthaler, Susanne M. ; Korber, Nikolaus
Date of publication of this fulltext: 16 Feb 2023 06:04

This publication is part of the DEAL contract with Wiley.


The titular compound [K([2.2.2]-crypt)]K[Pt3(μ2-CO)3(PPh3)3] ⋅ 3NH3 (1) ([2.2.2]-crypt=4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane) contains a triangular platinum complex, the approximate D3 symmetry of which is only broken by the phenyl substituents of the PPh3 ligands.. The dianionic complex represents only the second triangular carbonyl platinate characterized via single crystal ...


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