| Published Version Download ( PDF | 429kB) | License: Creative Commons Attribution Non-commercial No Derivatives 4.0 |
[K([2.2.2]‐crypt)]K[Pt 3 (μ 2 ‐CO) 3 (PPh 3 ) 3 ] ⋅ 3NH 3 – A New Chini ‐Type Platinum Carbonyl Complex
Tiefenthaler, Susanne M. and Korber, Nikolaus
(2022)
[K([2.2.2]‐crypt)]K[Pt 3 (μ 2 ‐CO) 3 (PPh 3 ) 3 ] ⋅ 3NH 3 – A New Chini ‐Type Platinum Carbonyl Complex.
Zeitschrift für anorganische und allgemeine Chemie 649 (3), e202200286.
Date of publication of this fulltext: 16 Feb 2023 06:04
Article
DOI to cite this document: 10.5283/epub.53787
Abstract
The titular compound [K([2.2.2]-crypt)]K[Pt-3(mu(2)-CO)(3)(PPh3)(3)] center dot 3NH(3) (1) ([2.2.2]-crypt=4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane) contains a triangular platinum complex, the approximate D-3 symmetry of which is only broken by the phenyl substituents of the PPh3 ligands.. The dianionic complex represents only the second triangular carbonyl platinate ...
The titular compound [K([2.2.2]-crypt)]K[Pt-3(mu(2)-CO)(3)(PPh3)(3)] center dot 3NH(3) (1) ([2.2.2]-crypt=4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane) contains a triangular platinum complex, the approximate D-3 symmetry of which is only broken by the phenyl substituents of the PPh3 ligands.. The dianionic complex represents only the second triangular carbonyl platinate characterized via single crystal X-ray diffraction in monomeric form. The compound crystallizes in the space group P (1) over bar with the unit cell parameters a=13.8826 angstrom, b=14.2899 angstrom and c=21.3254 angstrom. For the formation of the platinate, liquid ammonia seems to play a crucial role as a solvent for the polygermanide used for the reduction as well as for the stabilization of the dianion.
Alternative links to fulltext
Involved Institutions
Details
| Item type | Article | ||||
| Journal or Publication Title | Zeitschrift für anorganische und allgemeine Chemie | ||||
| Publisher: | WILEY-V C H VERLAG GMBH | ||||
|---|---|---|---|---|---|
| Place of Publication: | WEINHEIM | ||||
| Volume: | 649 | ||||
| Number of Issue or Book Chapter: | 3 | ||||
| Page Range: | e202200286 | ||||
| Date | 16 December 2022 | ||||
| Institutions | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber | ||||
| Identification Number |
| ||||
| Keywords | CRYSTAL-STRUCTURE; STRUCTURAL-CHARACTERIZATION; CLUSTERS; DIANIONS; SANDWICH; SILICON; SERIES; UNITS; Platinum; Carbonyl; Transition-Metallates; Zintl phases; Liquid ammonia | ||||
| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Yes | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-537871 | ||||
| Item ID | 53787 |
Download Statistics
Download Statistics