[K([2.2.2]‐crypt)]K[Pt 3 (μ 2 ‐CO) 3 (PPh 3 ) 3 ] ⋅ 3NH 3 – A New Chini ‐Type Platinum Carbonyl Complex - University of Regensburg Publication Server

URN to cite this document:: urn:nbn:de:bvb:355-epub-537871
DOI to cite this document:: 10.5283/epub.53787

Tiefenthaler, Susanne M. ; Korber, Nikolaus

License: Creative Commons Attribution Non-commercial No Derivatives 4.0
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Date of publication of this fulltext: 16 Feb 2023 06:04

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Abstract

The titular compound [K([2.2.2]-crypt)]K[Pt-3(mu(2)-CO)(3)(PPh3)(3)] center dot 3NH(3) (1) ([2.2.2]-crypt=4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane) contains a triangular platinum complex, the approximate D-3 symmetry of which is only broken by the phenyl substituents of the PPh3 ligands.. The dianionic complex represents only the second triangular carbonyl platinate ...