[K([2.2.2]‐crypt)]K[Pt 3 (μ 2 ‐CO) 3 (PPh 3 ) 3 ] ⋅ 3NH 3 – A New Chini ‐Type Platinum Carbonyl Complex - University of Regensburg Publication Server

URN to cite this document:: urn:nbn:de:bvb:355-epub-537871
DOI to cite this document:: 10.5283/epub.53787

Tiefenthaler, Susanne M. ; Korber, Nikolaus

License: Creative Commons Attribution Non-commercial No Derivatives 4.0
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Date of publication of this fulltext: 16 Feb 2023 06:04

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Abstract

The titular compound [K([2.2.2]-crypt)]K[Pt3(μ2-CO)3(PPh3)3] ⋅ 3NH3 (1) ([2.2.2]-crypt=4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane) contains a triangular platinum complex, the approximate D3 symmetry of which is only broken by the phenyl substituents of the PPh3 ligands.. The dianionic complex represents only the second triangular carbonyl platinate characterized via single crystal ...