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Energy Harvesting: Synthetic Use of Recovered Energy in Electrochemical Late-Stage Functionalization
Article
Karl, Tobias A.
, Seidl, Max and König, Burkhard
(2023)
Energy Harvesting: Synthetic Use of Recovered Energy in Electrochemical Late-Stage Functionalization.
ChemElectroChem, e202201097.
DOI to cite this document: 10.5283/epub.53789
This is the latest version of this item.
Abstract
An induction-based energy harvesting (EH) device was presented. It converted part of the rotational energy of magnetic stirrers back into electrical energy, making it accessible for electrochemical transformations. After rectification, the induced AC voltage was optionally provided as a constant voltage or constant current whereby the available voltage could directly be adjusted by the stirring ...
An induction-based energy harvesting (EH) device was presented. It converted part of the rotational energy of magnetic stirrers back into electrical energy, making it accessible for electrochemical transformations. After rectification, the induced AC voltage was optionally provided as a constant voltage or constant current whereby the available voltage could directly be adjusted by the stirring rate of the reaction. The comparability of the results with reactions carried out with commercial power supplies has been demonstrated on six different late-stage functionalization, including methylation, carboxylation, trifluoromethylation, imidation, hydrolysis, and keto-olefin coupling. Therefore, the described EH device is a low-cost, resource-efficient alternative to a commercial electrochemical set-up and enables laboratories without specialized equipment to perform electrochemical reactions.
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Details
| Item type | Article | ||||
| Journal or Publication Title | ChemElectroChem | ||||
| Publisher | Wiley | ||||
| Open Access Type | DEAL (Wiley Gold) | ||||
| Page Range | e202201097 | ||||
| Date | 13 January 2023 | ||||
| Date of publication | 15 Feb 2023 12:50 | ||||
| Institutions | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König | ||||
| Identification Number |
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| Keywords | Electrochemistry · Energy harvesting · Late-stage functionalization · Radicals · Self-sustaining | ||||
| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Yes | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-537895 | ||||
| Item ID | 53789 |
Available versions of this item
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Energy Harvesting: Synthetic Use of Recovered Energy in Electrochemical Late-Stage Functionalization. (Deposited on 19 Jan 2023 15:24)
- Energy Harvesting: Synthetic Use of Recovered Energy in Electrochemical Late-Stage Functionalization. (Deposited on 15 Feb 2023 12:50) [Currently displayed]
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