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Karl, Tobias A. ; Seidl, Max ; König, Burkhard

Energy Harvesting: Synthetic Use of Recovered Energy in Electrochemical Late-Stage Functionalization

Karl, Tobias A. , Seidl, Max and König, Burkhard (2023) Energy Harvesting: Synthetic Use of Recovered Energy in Electrochemical Late-Stage Functionalization. ChemElectroChem, e202201097.

Date of publication of this fulltext: 15 Feb 2023 12:50
Article
DOI to cite this document: 10.5283/epub.53789

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Abstract

An induction-based energy harvesting (EH) device was presented. It converted part of the rotational energy of magnetic stirrers back into electrical energy, making it accessible for electrochemical transformations. After rectification, the induced AC voltage was optionally provided as a constant voltage or constant current whereby the available voltage could directly be adjusted by the stirring ...

An induction-based energy harvesting (EH) device was presented. It converted part of the rotational energy of magnetic stirrers back into electrical energy, making it accessible for electrochemical transformations. After rectification, the induced AC voltage was optionally provided as a constant voltage or constant current whereby the available voltage could directly be adjusted by the stirring rate of the reaction. The comparability of the results with reactions carried out with commercial power supplies has been demonstrated on six different late-stage functionalization, including methylation, carboxylation, trifluoromethylation, imidation, hydrolysis, and keto-olefin coupling. Therefore, the described EH device is a low-cost, resource-efficient alternative to a commercial electrochemical set-up and enables laboratories without specialized equipment to perform electrochemical reactions.



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Details

Item typeArticle
Journal or Publication TitleChemElectroChem
Publisher:Wiley
Page Range:e202201097
Date13 January 2023
InstitutionsChemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Identification Number
ValueType
10.1002/celc.202201097DOI
KeywordsElectrochemistry · Energy harvesting · Late-stage functionalization · Radicals · Self-sustaining
Dewey Decimal Classification500 Science > 540 Chemistry & allied sciences
StatusPublished
RefereedYes, this version has been refereed
Created at the University of RegensburgYes
URN of the UB Regensburgurn:nbn:de:bvb:355-epub-537895
Item ID53789

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