Divergent Functionalization of Styrenes via Radical/Polar Crossover with CO2 and Sodium Sulfinates

URN to cite this document:: urn:nbn:de:bvb:355-epub-538914
DOI to cite this document:: 10.5283/epub.53891

Benedetti Vega, Kimberly

; Campos Delgado, José Antonio

; Pugnal, Lucas V. B. L.

; König, Burkhard

; Correia, José Tiago M.

; Weber Paixão, Márcio

PDF - Accepted Version
early view
(9MB)

Date of publication of this fulltext: 07 Mar 2023 13:39

Alternative links to fulltext:DOI Publisher

Details

Preview: early view

Export bibliographical data

Abstract

Sulfones and carboxylic acids are prominent motifs widely present in the chemical structure of agrochemicals, pharmaceuticals and many other highly valuable compounds. Herein, we describe a conjunctive strategy for the precise installation of these functionalities onto styrenes using sodium sulfinates and CO2 as coupling partners. The protocol allowed the preparation of carboxy-sulfonylated ...