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Divergent Functionalization of Styrenes via Radical/Polar Crossover with CO2 and Sodium Sulfinates

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Benedetti Vega, Kimberly ; Campos Delgado, José Antonio ; Pugnal, Lucas V. B. L. ; König, Burkhard ; Correia, José Tiago M. ; Weber Paixão, Márcio
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Date of publication of this fulltext: 07 Mar 2023 13:39


Sulfones and carboxylic acids are prominent motifs widely present in the chemical structure of agrochemicals, pharmaceuticals and many other highly valuable compounds. Herein, we describe a conjunctive strategy for the precise installation of these functionalities onto styrenes using sodium sulfinates and CO2 as coupling partners. The protocol allowed the preparation of carboxy-sulfonylated ...


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