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Bulking up CpBIG: A Penta-Terphenyl Cyclopentadienyl Ligand

URN to cite this document:
urn:nbn:de:bvb:355-epub-539969
DOI to cite this document:
10.5283/epub.53996
Hierlmeier, Gabriele ; Wolf, Robert
Date of publication of this fulltext: 29 Mar 2023 08:50



Abstract

The modification of cyclopentadienyl ligands with carefully selected substituents is a widely used strategy for tuning their steric and electronic properties. We describe the synthesis of an extremely bulky penta-terphenyl cyclopentadienyl ligand (CpT5) by arylation of cyclopentadiene. Deprotonation reactions with various group 1 metals and bases afforded a complete series of alkali metal salts ...

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