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Bulking up CpBIG: A Penta-Terphenyl Cyclopentadienyl Ligand

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Hierlmeier, Gabriele ; Wolf, Robert
Date of publication of this fulltext: 29 Mar 2023 08:50


The modification of cyclopentadienyl ligands withcarefully selected substituents is a widely used strategy for tuning theirsteric and electronic properties. We describe the synthesis of anextremely bulky penta-terphenyl cyclopentadienyl ligand (CpT5)byarylation of cyclopentadiene. Deprotonation reactions with variousgroup 1 metals and bases afforded a complete series of alkali metalsalts MCpT5(M ...


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