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Photocatalytic stannylation of white phosphorus

URN to cite this document:
urn:nbn:de:bvb:355-epub-539984
DOI to cite this document:
10.5283/epub.53998
Till, Marion ; Cammarata, Jose ; Wolf, Robert ; Scott, Daniel J.
[img]License: Creative Commons: Attribution 3.0
PDF - Published Version
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Date of publication of this fulltext: 30 Mar 2023 04:13



Abstract

Organophosphorus compounds (OPCs) are highly important chemicals, finding numerous applications in both academia and industry. Herein we describe a simple photocatalytic method for the stannylation of white phosphorus (P4) using a cheap, commercially-available distannane, (Bu3Sn)2, and anthraquinone as a simple photocatalyst. Subsequent ‘one pot’ transformation of the resulting stannylated ...

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