Copper(I) Photocatalyzed Bromonitroalkylation of Olefins: Evidence for Highly Efficient Inner‐Sphere Pathways

URN to cite this document:: urn:nbn:de:bvb:355-epub-540391
DOI to cite this document:: 10.5283/epub.54039

Reichle, Alexander ; Koch, Magdalena ; Sterzel, Hannes ; Großkopf, Lea‐Joy ; Floss, Johannes ; Rehbein, Julia

; Reiser, Oliver

License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 06 Apr 2023 09:36

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Abstract

We report the visible light-mediated copper-catalyzed vicinal difunctionalization of olefins utilizing bromonitroalkanes as ATRA reagents. This protocol is characterized by high yields and fast reaction times under environmentally benign reaction conditions with exceptional scope, allowing the rapid functionalization of both activated and unactivated olefins. Moreover, late-stage ...