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In situ Generated Copper(II)‐Quinoline Complexes as Robust and Versatile Photocatalysts for the Chlorosulfonylation of Olefins

URN to cite this document:
urn:nbn:de:bvb:355-epub-543791
DOI to cite this document:
10.5283/epub.54379
Chaibuth, Pawittra ; Engl, Sebastian ; Reichle, Alexander ; Chainok, Kittipong ; Sukwattanasinitt, Mongkol ; Reiser, Oliver
Date of publication of this fulltext: 15 Jun 2023 12:36

This publication is part of the DEAL contract with Wiley.


Abstract

A series of copper complexes was synthesized and studied as photocatalysts for the chlorosulfonylation of olefins. Featuring a tetradentate ligand consisting of one amino quinoline and two methyl pyridine moieties, the resulting Cu(II)-complex is effective under visible light irradiation to add sulfonyl chlorides to alkenes and alkynes, including unactivated aliphatic olefins. A weak base ...

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