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[(K,Rb)@([2.2.2]crypt)]2(K,Rb)4[Si9W(CO)4] ⋅ 13.4 NH3 – The First Tungsten Functionalized Silicon Zintl Cluster

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Braun, Paul A. ; Westermair, Franz F. ; Gschwind, Ruth M. ; Korber, Nikolaus
Date of publication of this fulltext: 29 Aug 2023 05:33

This publication is part of the DEAL contract with Wiley.


The reaction between the heteroleptic metal carbonyl complex [W(CO)4(tmeda)] ((tmeda)=N,N,N′,N′-Tetramethylethane-1,2-diamine) with [Si9]4− silicon Zintl clusters in presence of [2.2.2]crypt ([2.2.2]crypt=4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo[8.8.8]-hexacosane) in liquid ammonia yielded the compound [(K,Rb)@([2.2.2]crypt)]2(K,Rb)4[Si9W(CO)4] ⋅ 13.4 NH3. The compound was analyzed by single ...


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