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Formation of a Hexaphosphido Cobalt Complex through P−P Condensation

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Hoidn, Christian M. ; Trabitsch, Karolina ; Schwedtmann, Kai ; Taube, Clemens ; Weigand, Jan J. ; Wolf, Robert
Date of publication of this fulltext: 07 Sep 2023 05:04

This publication is part of the DEAL contract with Wiley.


The reaction between diphosphorus derivatives [(ClImDipp)P2(Dipp)]OTf (1[OTf]) and [(ClImDipp)P2(Dipp)Cl] (1[Cl]) with the cyclotetraphosphido cobalt complex [K(18c-6)][(PHDI)Co(η4-cyclo-P4)] (2) leads to the formation of complex [(PHDI)Co{η4-cyclo-P6(Dipp)(ClImDipp)}] (3), which features an unusual hexaphosphido ligand [ClImDipp=4,5-dichloro-1,3-bis(2,6-diisopropylphenyl)imidazol-2-yl, ...


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