Formation of a Hexaphosphido Cobalt Complex through P−P Condensation

URN to cite this document:: urn:nbn:de:bvb:355-epub-546721
DOI to cite this document:: 10.5283/epub.54672

Hoidn, Christian M. ; Trabitsch, Karolina ; Schwedtmann, Kai ; Taube, Clemens ; Weigand, Jan J. ; Wolf, Robert

License: Creative Commons Attribution Non-commercial 4.0
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Date of publication of this fulltext: 07 Sep 2023 05:04

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Abstract

The reaction between diphosphorus derivatives [(ClImDipp)P2(Dipp)]OTf (1[OTf]) and [(ClImDipp)P2(Dipp)Cl] (1[Cl]) with the cyclotetraphosphido cobalt complex [K(18c-6)][(PHDI)Co(η4-cyclo-P4)] (2) leads to the formation of complex [(PHDI)Co{η4-cyclo-P6(Dipp)(ClImDipp)}] (3), which features an unusual hexaphosphido ligand [ClImDipp=4,5-dichloro-1,3-bis(2,6-diisopropylphenyl)imidazol-2-yl, ...