Visible‐Light‐Triggered Photoswitching of Diphosphene Complexes

URN to cite this document:: urn:nbn:de:bvb:355-epub-549608
DOI to cite this document:: 10.5283/epub.54960

Taube, Clemens ; Fidelius, Jannis ; Schwedtmann, Kai ; Ziegler, Christopher ; Kreuter, Florian ; Loots, Leigh ; Barbour, Leonard J. ; Tonner‐Zech, Ralf ; Wolf, Robert

; Weigand, Jan J.

License: Creative Commons Attribution Non-commercial 4.0
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Date of publication of this fulltext: 09 Nov 2023 17:50

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Abstract

Although diphosphene transition metal complexes are known to undergo E to Z isomerization upon irradiation with UV light, their potential for photoswitching has remained poorly explored. In this study, we present diphosphene complexes capable of reversible photoisomerizations through haptotropic rearrangements. The compounds [(2-κ2P,κ6C)Mo(CO)2][OTf] (3 a[OTf]), [(2-κ2P,κ6C)Fe(CO)][OTf] ...