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Visible‐Light‐Triggered Photoswitching of Diphosphene Complexes

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Taube, Clemens ; Fidelius, Jannis ; Schwedtmann, Kai ; Ziegler, Christopher ; Kreuter, Florian ; Loots, Leigh ; Barbour, Leonard J. ; Tonner‐Zech, Ralf ; Wolf, Robert ; Weigand, Jan J.
Date of publication of this fulltext: 09 Nov 2023 17:50


Although diphosphene transition metal complexes are known to undergo E to Z isomerization upon irradiation with UV light, their potential for photoswitching has remained poorly explored. In this study, we present diphosphene complexes capable of reversible photoisomerizations through haptotropic rearrangements. The compounds [(2-κ2P,κ6C)Mo(CO)2][OTf] (3 a[OTf]), [(2-κ2P,κ6C)Fe(CO)][OTf] ...


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