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Dick, Bernhard ; Hochstrasser, Robin M.

Absorption and emission spectroscopies of homogeneous and inhomogeneously broadened multilevel systems in strong light fields

Dick, Bernhard und Hochstrasser, Robin M. (1984) Absorption and emission spectroscopies of homogeneous and inhomogeneously broadened multilevel systems in strong light fields. Journal of Chemical Physics 81 (7), S. 2897-2906.

Veröffentlichungsdatum dieses Volltextes: 05 Aug 2009 13:50
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.5516


Zusammenfassung

A method is introduced to calc., for a model set of mol. levels, the spectral line shapes expected for a variety of conventional laser expts. including absorption, hole burning, fluorescence line narrowing, and Raman scattering. The method allows the incident laser field to have arbitrary intensity. Furthermore, the effects of model gaussian or lorenzian inhomogeneous distributions are readily ...

A method is introduced to calc., for a model set of mol. levels, the spectral line shapes expected for a variety of conventional laser expts. including absorption, hole burning, fluorescence line narrowing, and Raman scattering. The method allows the incident laser field to have arbitrary intensity. Furthermore, the effects of model gaussian or lorenzian inhomogeneous distributions are readily incorporated. Earlier results for a 2-level system are easily obtained and new results are presented for inhomogeneously broadened 2- and 3-level systems, and for the effects of pure dephasing on the strong field spectra. The differences between fluorescence and Raman in strong fields, and the effect of strong fields on the spontaneous emission of inhomogeneously broadened transitions were described. Some predictions are made regarding line narrowing expts. in the strong-field limit.



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Details

DokumentenartArtikel
Titel eines Journals oder einer ZeitschriftJournal of Chemical Physics
Verlag:American Institute of Physics (AIP)
Band:81
Nummer des Zeitschriftenheftes oder des Kapitels:7
Seitenbereich:S. 2897-2906
Datum1984
Zusätzliche Informationen (Öffentlich)CAN 101:201024 73-10 Optical, Electron, and Mass Spectroscopy and Other Related Properties
InstitutionenChemie und Pharmazie > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Bernhard Dick
Identifikationsnummer
WertTyp
1984:601024Andere
10.1063/1.448064DOI
Stichwörter / KeywordsFluorescence (of multilevel systems, in strong light fields); Laser radiation (spectroscopy, of multilevel systems, in strong light fields); Spectrometry (laser, of multilevel systems, in strong light fields); laser spectroscopy multilevel system; absorption spectroscopy multilevel system; emission spectroscopy multilevel system; fluorescence line narrowing multilevel system; Raman strong field multilevel system
Dewey-Dezimal-Klassifikation500 Naturwissenschaften und Mathematik > 540 Chemie
StatusVeröffentlicht
BegutachtetJa, diese Version wurde begutachtet
An der Universität Regensburg entstandenNein
URN der UB Regensburgurn:nbn:de:bvb:355-epub-55163
Dokumenten-ID5516

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