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Absorption and emission spectroscopies of homogeneous and inhomogeneously broadened multilevel systems in strong light fields
Dick, Bernhard and Hochstrasser, Robin M. (1984) Absorption and emission spectroscopies of homogeneous and inhomogeneously broadened multilevel systems in strong light fields. Journal of Chemical Physics 81 (7), pp. 2897-2906.Date of publication of this fulltext: 05 Aug 2009 13:50
Article
DOI to cite this document: 10.5283/epub.5516
Abstract
A method is introduced to calc., for a model set of mol. levels, the spectral line shapes expected for a variety of conventional laser expts. including absorption, hole burning, fluorescence line narrowing, and Raman scattering. The method allows the incident laser field to have arbitrary intensity. Furthermore, the effects of model gaussian or lorenzian inhomogeneous distributions are readily ...
A method is introduced to calc., for a model set of mol. levels, the spectral line shapes expected for a variety of conventional laser expts. including absorption, hole burning, fluorescence line narrowing, and Raman scattering. The method allows the incident laser field to have arbitrary intensity. Furthermore, the effects of model gaussian or lorenzian inhomogeneous distributions are readily incorporated. Earlier results for a 2-level system are easily obtained and new results are presented for inhomogeneously broadened 2- and 3-level systems, and for the effects of pure dephasing on the strong field spectra. The differences between fluorescence and Raman in strong fields, and the effect of strong fields on the spontaneous emission of inhomogeneously broadened transitions were described. Some predictions are made regarding line narrowing expts. in the strong-field limit.
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| Item type | Article | ||||||
| Journal or Publication Title | Journal of Chemical Physics | ||||||
| Publisher: | American Institute of Physics (AIP) | ||||||
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| Volume: | 81 | ||||||
| Number of Issue or Book Chapter: | 7 | ||||||
| Page Range: | pp. 2897-2906 | ||||||
| Date | 1984 | ||||||
| Additional Information (public) | CAN 101:201024 73-10 Optical, Electron, and Mass Spectroscopy and Other Related Properties | ||||||
| Institutions | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Bernhard Dick | ||||||
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| Keywords | Fluorescence (of multilevel systems, in strong light fields); Laser radiation (spectroscopy, of multilevel systems, in strong light fields); Spectrometry (laser, of multilevel systems, in strong light fields); laser spectroscopy multilevel system; absorption spectroscopy multilevel system; emission spectroscopy multilevel system; fluorescence line narrowing multilevel system; Raman strong field multilevel system | ||||||
| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||||
| Status | Published | ||||||
| Refereed | Yes, this version has been refereed | ||||||
| Created at the University of Regensburg | No | ||||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-55163 | ||||||
| Item ID | 5516 |
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