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Side-Selective Solid-Phase Metallaphotoredox N(in)-Arylation of Peptides

Delgado, José A. C. ; Tian, Ya-Ming ; Marcon, Michela ; König, Burkhard ; Paixão, Márcio W.


Postsynthetic diversification of peptides through selective modification of endogenous amino acid side chains has enabled significant advances in peptide drug discovery while expanding the biological and medical chemistry space. However, current tools have been focused on the modification of reactive polar and ionizable side chains, whereas the decoration of aromatic systems (e.g., the N(in) of ...


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