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Cobalt‐Mediated [3+1] Fragmentation of White Phosphorus: Access to Acylcyanophosphanides

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Hauer, Sebastian ; Horsley Downie, Thomas M. ; Balázs, Gábor ; Schwedtmann, Kai ; Weigand, Jan J. ; Wolf, Robert
Date of publication of this fulltext: 09 Jan 2024 05:33

This publication is part of the DEAL contract with Wiley.


Despite the accessibility of numerous transition metal polyphosphido complexes through transition-metal-mediated activation of white phosphorus, the targeted functionalization of Pn ligands to obtain functional monophosphorus species remains challenging. In this study, we introduce a new [3+1] fragmentation procedure for cyclo-P4 ligands, leading to the discovery of acylcyanophosphanides and ...


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