Cobalt‐Mediated [3+1] Fragmentation of White Phosphorus: Access to Acylcyanophosphanides

URN to cite this document:: urn:nbn:de:bvb:355-epub-552999
DOI to cite this document:: 10.5283/epub.55299

Hauer, Sebastian

; Horsley Downie, Thomas M.

; Balázs, Gábor

; Schwedtmann, Kai ; Weigand, Jan J. ; Wolf, Robert

License: Creative Commons Attribution Non-commercial 4.0
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Date of publication of this fulltext: 09 Jan 2024 05:33

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Abstract

Despite the accessibility of numerous transition metal polyphosphido complexes through transition-metal-mediated activation of white phosphorus, the targeted functionalization of Pn ligands to obtain functional monophosphorus species remains challenging. In this study, we introduce a new [3+1] fragmentation procedure for cyclo-P4 ligands, leading to the discovery of acylcyanophosphanides and ...