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Counterion Effect in Cobaltate‐Catalyzed Alkene Hydrogenation

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Gawron, Martin ; Gilch, Franziska ; Schmidhuber, Daniel ; Kelly, John A. ; Horsley Downie, Thomas M. ; Jacobi von Wangelin, Axel ; Rehbein, Julia ; Wolf, Robert
Date of publication of this fulltext: 09 Jan 2024 05:47

This publication is part of the DEAL contract with Wiley.


We show that countercations exert a remarkable influence on the ability of anionic cobaltate salts to catalyze challenging alkene hydrogenations. An evaluation of the catalytic properties of [Cat][Co(η4-cod)2] (Cat=K (1), Na (2), Li (3), (Depnacnac)Mg (4), and N(nBu)4 (5); cod=1,5-cyclooctadiene, Depnacnac={2,6-Et2C6H3NC(CH3)}2CH)]) demonstrated that the lithium salt 3 and magnesium salt 4 ...


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