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X-ray photoemission study of satellite structure accompanying core ionization from coordinated nitrogen
Freund, Hans Joachim, Pulm, Harald, Dick, Bernhard und Lange, Ralph (1983) X-ray photoemission study of satellite structure accompanying core ionization from coordinated nitrogen. Chemical Physics 81 (1-2), S. 99-112.Veröffentlichungsdatum dieses Volltextes: 05 Aug 2009 13:50
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DOI zum Zitieren dieses Dokuments: 10.5283/epub.5547
Zusammenfassung
The core ionization was compared of free and adsorbed N2 to N2 bound head-on (with a linear N2-metal bond) to a metal atom in a mononuclear organometallic compd., namely h5-dicarbonyl-cyclopentadienyl-dinitrogen-manganese(I). A comprehensive assignment is given for the full spectrum including main lines and satellite lines on the basis of numerical calcns. The conclusions were compared to those ...
The core ionization was compared of free and adsorbed N2 to N2 bound head-on (with a linear N2-metal bond) to a metal atom in a mononuclear organometallic compd., namely h5-dicarbonyl-cyclopentadienyl-dinitrogen-manganese(I). A comprehensive assignment is given for the full spectrum including main lines and satellite lines on the basis of numerical calcns. The conclusions were compared to those earlier derived for CO complexes and adsorbates. The importance of doubly excited configurations for a correct description of the satellite excitation energies is discussed.
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| Dokumentenart | Artikel | ||||||
| Titel eines Journals oder einer Zeitschrift | Chemical Physics | ||||||
| Verlag: | Elsevier | ||||||
|---|---|---|---|---|---|---|---|
| Band: | 81 | ||||||
| Nummer des Zeitschriftenheftes oder des Kapitels: | 1-2 | ||||||
| Seitenbereich: | S. 99-112 | ||||||
| Datum | 1983 | ||||||
| Zusätzliche Informationen (Öffentlich) | CAN 99:218951 65-5 General Physical Chemistry 38600-58-7 Role: PRP (Properties) (core ionization of nitrogen mol. in); 7727-37-9 Role: PRP (Properties) (core ionization of, effect of manganese coordination on) | ||||||
| Institutionen | Chemie und Pharmazie > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Bernhard Dick | ||||||
| Identifikationsnummer |
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| Stichwörter / Keywords | Electron configuration; Energy level excitation (of manganese dicarbonyl cyclopentadienyl dinitrogen complex); Ionization potential and energy (inner-shell, of nitrogen in free state and coordinated to manganese with dicarbonyl and cyclopentadienyl); core ionization nitrogen manganese coordinated; carbonyl cyclopentadienyl manganese nitrogen ionization | ||||||
| Dewey-Dezimal-Klassifikation | 500 Naturwissenschaften und Mathematik > 540 Chemie | ||||||
| Status | Veröffentlicht | ||||||
| Begutachtet | Ja, diese Version wurde begutachtet | ||||||
| An der Universität Regensburg entstanden | Nein | ||||||
| URN der UB Regensburg | urn:nbn:de:bvb:355-epub-55479 | ||||||
| Dokumenten-ID | 5547 |
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