Kessler, Angela, Slenczka, Alkwin, Seiler, Reinhold and Dick, Bernhard (2001) The UV-photodissociation of jet-cooled nitrosobenzene studied by fluorescence excitation spectroscopy of the NO fragment. Physical Chemistry Chemical Physics 3 (14), pp. 2819-2830.
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Abstract
Monomeric nitrosobenzene was cooled in a supersonic jet and photolyzed with a tunable laser by excitation into the first and second UV absorption bands corresponding to the second and higher excited singlet states (Sn, n>=2). The populations of the rotational and vibrational states of the NO fragment were probed by fluorescence excitation spectroscopy with a second laser. No alignment of the ...
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| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 2001 | ||||
| Additional Information (public): | CAN 135:264400 74-1 Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes 2396-01-2 (Phenyl radical) Role: FMU (Formation, unclassified), PEP (Physical, engineering or chemical process), FORM (Formation, nonpreparative), PROC (Process) (photofragment; UV-photodissocn. of jet-cooled nitrosobenzene studied by fluorescence excitation spectroscopy of NO fragment); 10102-43-9 (Nitrogen oxide(NO) Role: FMU (Formation, unclassified), PEP (Physical, engineering or chemical process), PRP (Properties), FORM (Formation, nonpreparative), PROC (Process) (rotational and vibrational states of NO fragment in photolysis of jet-cooled nitrosobenzene studied by fluorescence excitation spectroscopy); 586-96-9 (Nitrosobenzene) Role: PEP (Physical, engineering or chemical process), RCT (Reactant), PROC (Process), RACT (Reactant or reagent) (rotational and vibrational states of NO fragment in photolysis of jet-cooled nitrosobenzene studied by fluorescence excitation spectroscopy) | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Bernhard Dick Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Alkwin Slenczka | ||||
| Identification Number: |
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| Keywords: | Electronic state; Translational energy (UV-photodissocn. of jet-cooled nitrosobenzene studied by fluorescence excitation spectroscopy of NO fragment); Photolysis (dynamics, rotational and vibrational states of NO fragment in photolysis of jet-cooled nitrosobenzene studied by fluorescence excitation spectroscopy); Rotational energy; Singlet state excitation; Vibrational energy (rotational and vibrational states of NO fragment in photolysis of jet-cooled nitrosobenzene studied by fluorescence excitation spectroscopy); photodissocn nitrosobenzene fluorescence excitation spectroscopy nitrogen oxide photofragment; photolysis dynamics nitrosobenzene photofragment isotropic velocity distribution | ||||
| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 5559 |
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