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The UV-photodissociation of jet-cooled nitrosobenzene studied by fluorescence excitation spectroscopy of the NO fragment

Kessler, Angela ; Slenczka, Alkwin ; Seiler, Reinhold ; Dick, Bernhard



Abstract

Monomeric nitrosobenzene was cooled in a supersonic jet and photolyzed with a tunable laser by excitation into the first and second UV absorption bands corresponding to the second and higher excited singlet states (Sn, n>=2). The populations of the rotational and vibrational states of the NO fragment were probed by fluorescence excitation spectroscopy with a second laser. No alignment of the ...

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