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Photooxidation driven formation of Fe-Au linked ferrocene-based single-molecule junctions

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Lee, Woojung ; Li, Liang ; Camarasa-Gómez, María ; Hernangómez-Pérez, Daniel ; Roy, Xavier ; Evers, Ferdinand ; Inkpen, Michael S. ; Venkataraman, Latha
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Date of publication of this fulltext: 27 Feb 2024 05:57


Metal-metal contacts, though not yet widely realized, may provide exciting opportunities to serve as tunable and functional interfaces in single-molecule devices. One of the simplest components which might facilitate such binding interactions is the ferrocene group. Notably, direct bonds between the ferrocene iron center and metals such as Pd or Co have been demonstrated in molecular complexes ...


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