This work covers several topics related to ion- and solvent effects.

In addition to background information from literature, further findings and unpublished results it mainly deals with the results from:

(1) Dullinger, P.; Horinek, D. Solvation of Nanoions in Aqueous Solutions. J. Am. Chem. Soc. 2023, 145 (45), 24922–24930. https://doi.org/10.1021/jacs.3c09494.

(2) Gramüller, J.; Dullinger, P.; Horinek, D.; Gschwind, R. M. Bidentate Substrate Binding in Brønsted Acid Catalysis: Structural Space, Hydrogen Bonding and Dimerization. Chem. Sci. 2022. https://doi.org/10.1039/D2SC05076E.

(3) Arnold, A. M.; Dullinger, P.; Biswas, A.; Jandl, C.; Horinek, D.; Gulder, T. Enzyme-like Polyene Cyclizations Catalyzed by Dynamic, Self-Assembled, Supramolecular Fluoro Alcohol-Amine Clusters. Nat Commun 2023, 14 (1), 813. https://doi.org/10.1038/s41467-023-36157-0.

(4) Park, S.; Dutta, A. K.; Allacher, C.; Abramov, A.; Dullinger, P.; Kuzmanoska, K.; Fritsch, D.; Hitzfeld, P.; Horinek, D.; Rehbein, J.; Nuernberger, P.; Gschwind, R. M.; Breder, A. Hydrogen-Bond-Modulated Nucleofugality of SeIII Species to Enable Photoredox-Catalytic Semipinacol Manifolds. Angewandte Chemie International Edition 2022, 61 (49), e202208611. https://doi.org/10.1002/anie.202208611.

Diese Arbeit behandelt verschiedene Themen bezüglich Ionen- und Solvenseffekten.

Zusätzlich zu Literaturhintergrundinformationen, weiteren Ergebnissen und unveröffentlichen Resultaten werden hauptsächlich die Resultate aus den folgenden Publikationen behandelt:

(1) Dullinger, P.; Horinek, D. Solvation of Nanoions in Aqueous Solutions. J. Am. Chem. Soc. 2023, 145 (45), 24922–24930. https://doi.org/10.1021/jacs.3c09494.

(2) Gramüller, J.; Dullinger, P.; Horinek, D.; Gschwind, R. M. Bidentate Substrate Binding in Brønsted Acid Catalysis: Structural Space, Hydrogen Bonding and Dimerization. Chem. Sci. 2022. https://doi.org/10.1039/D2SC05076E.

(3) Arnold, A. M.; Dullinger, P.; Biswas, A.; Jandl, C.; Horinek, D.; Gulder, T. Enzyme-like Polyene Cyclizations Catalyzed by Dynamic, Self-Assembled, Supramolecular Fluoro Alcohol-Amine Clusters. Nat Commun 2023, 14 (1), 813. https://doi.org/10.1038/s41467-023-36157-0.

(4) Park, S.; Dutta, A. K.; Allacher, C.; Abramov, A.; Dullinger, P.; Kuzmanoska, K.; Fritsch, D.; Hitzfeld, P.; Horinek, D.; Rehbein, J.; Nuernberger, P.; Gschwind, R. M.; Breder, A. Hydrogen-Bond-Modulated Nucleofugality of SeIII Species to Enable Photoredox-Catalytic Semipinacol Manifolds. Angewandte Chemie International Edition 2022, 61 (49), e202208611. https://doi.org/10.1002/anie.202208611.