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Velocity-map ion-imaging of the NO fragment from the UV-photodissociation of nitrosobenzene

Obernhuber, Thorsten J., Kensy, Uwe und Dick, Bernhard (2003) Velocity-map ion-imaging of the NO fragment from the UV-photodissociation of nitrosobenzene. Physical Chemistry Chemical Physics 5 (13), S. 2799-2806.

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Zusammenfassung

The velocity and angular distribution of NO fragments produced by UV photodissocn. of nitrosobenzene have been detd. by velocity-map ion-imaging. Excitation of the S2-state by irradn. into the peak of the first UV absorption band at 290.5 nm leads to a completely isotropic velocity distribution with Gaussian shape. The av. kinetic energy in both fragments correlates with the rotational energy of ...

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Dokumentenart:Artikel
Datum:2003
Zusätzliche Informationen (Öffentlich):CAN 139:267843 74-1 Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes 2396-01-2 (Phenyl radical); 7782-44-7 (Oxygen); 10102-43-9 (Nitrogen monoxide); 14452-93-8 (Nitrogen monoxide ion(1+) Role: CPS (Chemical process), FMU (Formation, unclassified), PEP (Physical, engineering or chemical process), PRP (Properties), FORM (Formation, nonpreparative), PROC (Process) (velocity-map ion-imaging of NO fragment from UV-photodissocn. of nitrosobenzene); 586-96-9 (Nitrosobenzene) Role: CPS (Chemical process), PEP (Physical, engineering or chemical process), PRP (Properties), RCT (Reactant), PROC (Process), RACT (Reactant or reagent) (velocity-map ion-imaging of NO fragment from UV-photodissocn. of nitrosobenzene); 10102-44-0 (Nitrogen oxide (NO2) Role: CPS (Chemical process), PEP (Physical, engineering or chemical process), PRP (Properties), RCT (Reactant), PROC (Process), RACT (Reactant or reagent) (velocity-map ion-imaging of NO fragment from UV-photodissocn. of nitrosobenzene in relation to photodissocn. of)
Institutionen:Chemie und Pharmazie > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Bernhard Dick
Identifikationsnummer:
WertTyp
2003:468877Andere
Stichwörter / Keywords:Angular distribution function; Photoionization; Photolysis; Singlet state transition; Velocity (velocity-map ion-imaging of NO fragment from UV-photodissocn. of nitrosobenzene); photodissocn UV nitrosobenzene velocity map ion imaging
Dewey-Dezimal-Klassifikation:500 Naturwissenschaften und Mathematik > 540 Chemie
Status:Veröffentlicht
Begutachtet:Ja, diese Version wurde begutachtet
An der Universität Regensburg entstanden:Ja
Eingebracht am:19 Jan 2009 13:22
Zuletzt geändert:24 Mai 2018 10:11
Dokumenten-ID:5571
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