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Velocity-map ion-imaging of the NO fragment from the UV-photodissociation of nitrosobenzene

Obernhuber, Thorsten J. ; Kensy, Uwe ; Dick, Bernhard


The velocity and angular distribution of NO fragments produced by UV photodissocn. of nitrosobenzene have been detd. by velocity-map ion-imaging. Excitation of the S2-state by irradn. into the peak of the first UV absorption band at 290.5 nm leads to a completely isotropic velocity distribution with Gaussian shape. The av. kinetic energy in both fragments correlates with the rotational energy of ...


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