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Velocity-map ion-imaging of the NO fragment from the UV-photodissociation of nitrosobenzene

Obernhuber, Thorsten J., Kensy, Uwe and Dick, Bernhard (2003) Velocity-map ion-imaging of the NO fragment from the UV-photodissociation of nitrosobenzene. Physical Chemistry Chemical Physics 5 (13), pp. 2799-2806.

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Abstract

The velocity and angular distribution of NO fragments produced by UV photodissocn. of nitrosobenzene have been detd. by velocity-map ion-imaging. Excitation of the S2-state by irradn. into the peak of the first UV absorption band at 290.5 nm leads to a completely isotropic velocity distribution with Gaussian shape. The av. kinetic energy in both fragments correlates with the rotational energy of ...

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Item type:Article
Date:2003
Additional Information (public):CAN 139:267843 74-1 Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes 2396-01-2 (Phenyl radical); 7782-44-7 (Oxygen); 10102-43-9 (Nitrogen monoxide); 14452-93-8 (Nitrogen monoxide ion(1+) Role: CPS (Chemical process), FMU (Formation, unclassified), PEP (Physical, engineering or chemical process), PRP (Properties), FORM (Formation, nonpreparative), PROC (Process) (velocity-map ion-imaging of NO fragment from UV-photodissocn. of nitrosobenzene); 586-96-9 (Nitrosobenzene) Role: CPS (Chemical process), PEP (Physical, engineering or chemical process), PRP (Properties), RCT (Reactant), PROC (Process), RACT (Reactant or reagent) (velocity-map ion-imaging of NO fragment from UV-photodissocn. of nitrosobenzene); 10102-44-0 (Nitrogen oxide (NO2) Role: CPS (Chemical process), PEP (Physical, engineering or chemical process), PRP (Properties), RCT (Reactant), PROC (Process), RACT (Reactant or reagent) (velocity-map ion-imaging of NO fragment from UV-photodissocn. of nitrosobenzene in relation to photodissocn. of)
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Bernhard Dick
Identification Number:
ValueType
2003:468877Other
Keywords:Angular distribution function; Photoionization; Photolysis; Singlet state transition; Velocity (velocity-map ion-imaging of NO fragment from UV-photodissocn. of nitrosobenzene); photodissocn UV nitrosobenzene velocity map ion imaging
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:5571
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