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1,6-Methano[10]annulene has a delocalized structure in S0 and S1: high-resolution spectroscopy in a supersonic jet

Seiler, Reinhold and Dick, Bernhard (2001) 1,6-Methano[10]annulene has a delocalized structure in S0 and S1: high-resolution spectroscopy in a supersonic jet. Angewandte Chemie, International Edition 40 (21), pp. 4020-4023.

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Abstract

The vibrational structure of the excited electronic state of 1,6-methanol[10]annulene (MA) was measured to confirm the assumption of the delocalized structure of the ground state. If the ground state of MA had an energetic double min., then the electronic excitation would necessitate significant electronic structural changes. A quant. anal. of the band shapes yields rotational consts. for S0 and ...

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Item type:Article
Date:2001
Additional Information (public):CAN 136:118100 22-3 Physical Organic Chemistry 2443-46-1 (1,6-Methano[10]annulene) Role: PRP (Properties) (vibrational structure of excited electronic state of methano[10]annulene and delocalized structure of ground singlet state)
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Bernhard Dick
Identification Number:
ValueType
2001:849045Other
Keywords:Singlet state (ground state vibrational structure of excited electronic state of methano[10]annulene and delocalized structure of ground singlet state); Excited singlet state; Ground state; Vibronic transition (vibrational structure of excited electronic state of methano[10]annulene and delocalized structure of ground singlet state); methanoannulene ground singlet state delocalized structure vibrational structure excited singlet state methanoannulene
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:5575
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