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1,6-Methano[10]annulene has a delocalized structure in S0 and S1: high-resolution spectroscopy in a supersonic jet

Seiler, Reinhold ; Dick, Bernhard


The vibrational structure of the excited electronic state of 1,6-methanol[10]annulene (MA) was measured to confirm the assumption of the delocalized structure of the ground state. If the ground state of MA had an energetic double min., then the electronic excitation would necessitate significant electronic structural changes. A quant. anal. of the band shapes yields rotational consts. for S0 and ...


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