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Alignment and velocity distribution of the NO fragments from the UV photodissociation of jet-cooled nitrosobenzene studied by LIF and Doppler profile measurements

Seiler, Reinhold and Dick, Bernhard (2003) Alignment and velocity distribution of the NO fragments from the UV photodissociation of jet-cooled nitrosobenzene studied by LIF and Doppler profile measurements. Chemical Physics 288 (1), pp. 43-50.

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Abstract

The velocity distribution and alignment of the NO fragments produced by UV photodissocn. of nitrosobenzene have been studied by LIF measurements of Doppler profiles and polarization. The S2 and S3 states of nitrosobenzene were excited by irradn. into the first and second UV absorption bands at 290 and 266 nm, resp. No alignment could be detected. All Doppler profiles studied with rotational ...

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Item type:Article
Date:2003
Additional Information (public):CAN 138:346410 74-13 Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes 10102-43-9 (Nitrogen monoxide) Role: FMU (Formation, unclassified), PEP (Physical, engineering or chemical process), PRP (Properties), PYP (Physical process), FORM (Formation, nonpreparative), PROC (Process) (velocity distribution and alignment of NO fragments produced by UV photodissocn. of nitrosobenzene); 586-96-9 (Nitrosobenzene) Role: PRP (Properties), RCT (Reactant), RACT (Reactant or reagent) (velocity distribution and alignment of NO fragments produced by UV photodissocn. of nitrosobenzene)
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Bernhard Dick
Identification Number:
ValueType
2003:242830Other
Keywords:Rotational transition (of NO photoproduct velocity distribution and alignment of NO fragments produced by UV photodissocn. of nitrosobenzene); Rotational state (population distribution, velocity distribution and alignment of NO fragments produced by UV photodissocn. of nitrosobenzene); Singlet state excitation (upper, velocity distribution and alignment of NO fragments produced by UV photodissocn. of nitrosobenzene); Electronic transition; Laser induced fluorescence; Molecular orientation; Photolysis (velocity distribution and alignment of NO fragments produced by UV photodissocn. of nitrosobenzene); nitrosobenzene photodissocn dynamics photofragment alignment velocity distribution; photolysis nitrosobenzene upper singlet state excitation
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:5576
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