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Fluorescence excitation and UV-UV double-resonance spectroscopy of the S0 -> S1(Lb) transition of 1,6-methano[10]annulene cooled in a supersonic jet - Dedicated to Professor F. Doerr on the occasion of his 80th birthday

Seiler, Reinhold ; Kensy, Uwe ; Dick, Bernhard



Abstract

The 1st electronic singlet transition S0 -> S1 of the 10p-arom. compd. 1,6-methano[10]annulene (MA) cooled in a supersonic jet was studied up to an excess energy of 4000 cm-1. The strongest line at 25,154 cm-1 is assigned as the electronic origin. Anal. of the rotational envelope of this line proved that the transition dipole is parallel to the long axis of the mol. Optical-optical double ...

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