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Unusual Coordination Pattern of the Lithium Center in a Chiral α-Lithiated Silicon Compound

Bauer, Jonathan O. ; Strohmann, Carsten


An understanding of how stereogenic centers can influence the construction of a new metalated chirality center requires profound investigations concerning coordination and aggregation effects. A racemic silicon-stereogenic aminomethoxysilane (2) was chosen as the starting compound, which is additionally equipped with a (trimethylsilyl)methylene bridge and an aminomethyl function. Metalation of 2 ...


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