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Synthesis, structure, and catalytic activity of dinuclear aluminium bis(amidinate) and bis(guanidinate) complexes

Rösch, Andreas ; Seifert, Fabian ; Vass, Valentin ; Görls, Helmar ; Kretschmer, Robert


Eight dinuclear methyl aluminium(iii) bis(amidinate) and bis(guanidinate) complexes have been synthesized in good to very good yields and were fully characterized by means of H-1, C-13, and IR spectroscopy as well as elemental analysis. Five of them were successfully converted to the respective dinuclear aluminium iodide complexes and a dinuclear aluminium chloride bis(amidinate) complex was ...


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