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Click Chemistry in Ultra‐high Vacuum – Tetrazine Coupling with Methyl Enol Ether Covalently Linked to Si(001)

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Glaser, Timo ; Meinecke, Jannick ; Freund, Lukas ; Länger, Christian ; Luy, Jan‐Niclas ; Tonner, Ralf ; Koert, Ulrich ; Dürr, Michael
Date of publication of this fulltext: 29 Feb 2024 12:28


The additive-free tetrazine/enol ether click reaction was performed in ultra-high vacuum (UHV) with an enol ether group covalently linked to a silicon surface: Dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate molecules were coupled to the enol ether group of a functionalized cyclooctyne which was adsorbed on the silicon (001) surface via the strained triple bond of cyclooctyne. The reaction was ...


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