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Combined XPS and DFT investigation of the adsorption modes of methyl enol ether functionalized cyclooctyne on Si(001)

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Glaser, Timo ; Meinecke, Jannick ; Länger, Christian ; Luy, Jan‐Niclas ; Tonner, Ralf ; Koert, Ulrich ; Dürr, Michael
Date of publication of this fulltext: 29 Feb 2024 12:28


The reaction of methyl enol ether functionalized cyclooctyne on the silicon (001) surface was investigated by means of X-ray photoelectron spectroscopy (XPS) and density functional theory (DFT). Three different groups of final states were identified; all of them bind on Si(001) via the strained triple bond of cyclooctyne but they differ in the configuration of the methyl enol ether group. The ...


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