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Influence of Amino Functions on the Coordination Ability of Silyl Ethers and Disiloxanes

Bauer, Jonathan O.



Abstract

Amino-functionalized silyl ethers and siloxanes are a synthetically highly valuable class of compounds. The Si-N bond was studied with regard to its possible electronic influence on Si- O bonds in silyl ethers and disiloxanes. A thermochemical investigation of the deaggregation of a tBuLi tetramer using a variably patterned ligand collection was carried out by means of density functional theory ...

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