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A homoleptic tris(diphosphacyclobutadiene) tripledecker sandwich complex

Rödl, Christian ; Hierlmeier, Gabriele ; Wolf, Robert



Abstract

The synthesis and characterisation of [Co-2(eta(4)-P(2)C(2)tBu(2))(2)(mu:eta(4):eta(4)-P(2)C(2)tBu(2))] (1) is described, featuring two cobalt atoms and three diphosphacyclobutadiene ligands. This compound is the first triple-decker sandwich complex which exclusively contains cyclobutadiene ligands.


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