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Short alpha/beta-peptides as catalysts for intra- and intermolecular aldol reactions

D'Elia, V. ; Zwicknagl, H. ; Reiser, O.


Short alpha/beta-peptides, containing conformationally restricted cis-beta-aminocyclopropylcarboxylic acid units as turn-inducing elements, have been found to be efficient catalysts for inter- and intramolecular aldol reactions. The tripeptide H-(L)-Pro-triangle-(L)-Pro-OH was identified to perform especially well in homogeneous and heterogeneous aqueous solutions as well as in organic solvents.

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