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TEMPO Supported on Magnetic C/Co-Nanoparticles: A Highly Active and Recyclable Organocatalyst

Schatz, A. ; Grass, R. N. ; Stark, W. J. ; Reiser, O.



Abstract

TEMPO was grafted on graphene-coated nanobeads with a magnetic cobalt core by using a general applicable "click"-chemistry protocol. The new heterogeneous CoNP-TEMPO emerged as a highly active catalyst for the chemoselective oxidation of primary and secondary alcohols using bleach as terminal oxidant. The outstanding stability of the C/Co nanoparticles enables the nanopowder to tolerate several ...

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